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Chapter 19 Oxidation and Reduction Reactions Vocab

Adapted and/or taken from Holt Modern Chemistry 1999

AB
Anodein both electrolytic and voltaic cells it is the electrode where oxidation takes place (that is where a species loses an electron) (607); it is negative in voltaic cells, and positive in electrolytic cells
Autooxidationa process in which a substance acts as both an oxidizing agent and a reducing agent (605)
Cathodein both electrolytic cells and voltaic cells it is the electrode where reduction takes place; that is where species gain electrons (their oxidation number is reduced by adding negative electrons) (607) It is positive in voltaic cells, and negative in electrolytic cells
Electrochemical Cella system of electrodes and electrolytes in which either chemical reactions produce electrical energy or an electric current produces chemical change (607)
Electrochemistrythe branch of chemistry that deals with electricity-related applications of oxidation-reduction reactions (606)
Electrodea conductor used to establish electrical contact with a nonmetallic part of a circuit, such as an electrolyte (607)
Electrode Potentialthe difference in potential between an electrode and its solution (613)
Electrolysisthe process in which an electric current is used to produce an oxidation-reduction reaction (610)
Electrolytic Cellan electrochemical cell in which electrical energy is required to produce a redox reaction and FORCE a NON-SPONTANEOUS chemical change (610)
Electroplatingan electrolytic process in which a metal ion is reduced and solid metal is deposited on a surface (611)
Half-Cella single electrode immersed in a solution of its ions (607)
Half-Reactionthe part of a reaction involving oxidation or reduction alone (593)
Oxidationa reaction in which the atoms or ions of an element experience an increase in oxidation state (i.e. the oxidation number goes up b/c of the loss of a negatively charged electron) (592); LEO, Lose Electron(s) = Oxidized [LEO] LEO the lion says GER
Oxidation-Reduction Reactionany chemical process in which elements undergo changes in oxidation number (593)
Oxidizedhaving experienced an increase in oxidation number (i.e. a species that lost negative electrons, will now have a higher oxidation number) (592) ); LEO, Lose Electron(s) = Oxidized [LEO]
Oxidizing Agenta substance that has the potential to cause another substance to be oxidized (causing the other substance to lose electron(s) (602) The oxidizing agent is itself reduced when it reacts.
Redox Reactionany chemical process in which elements undergo changes in oxidation number (593)
Reducedhaving experienced a decrease in oxidation state (593) (a species that has gained negative electron(s) will have a lower oxidation number, or a REDUCED oxidation number. [GER: Gain Electron(s) Reduced: GER] LEO the lion says GER
Reducing Agenta substance that has the potential to cause another substance to be reduced (to gain electrons) (602); Reducing agents themselves are oxidized, but cause the reduction of anothe species, basically they give electrons to someone else)
Reductiona reaction in which the oxidation state of an element decreases (593) [GER: Gain Electron(s) Reduced: GER] LEO the lion says GER
Reduction Potentialthe measurement of the tendency for a half-reaction to occur as a reduction half-reaction in an electrochemical cell (613) (given in volts)
Standard Electrode Potentiala half-cell potential measured relative to a potential of zero for the standard hydrogen electrode (614)
Voltaic Cellan electrochemical cell in which the redox reaction occurs naturally and produces electrical energy (608)


Timberlane Regional High School
Plaistow, NH

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