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Chapter 9 AP Chem Flashcards

AB
sp^3 hybridizationFour new orbitals formed from one 2s and three 2p orbitals.
hybrid orbitalsA set of atomic orbitals adopted by an atom in a molecule different from those of the atom in the free state.
sp^2 hybridizationThree orbitals arranged at 120 degree angles formed from one 2s and two 2p orbitals.
sigma bondA covalent bond in which the electron pair is shared in an area contered on a line running between the atoms.
pi bondA covalent bond in which parallel p orbitals share an electron pair occupying the space above and below the line joining the atoms.
sp hybridizationTwo hybrid orbitals arranged at 180 degrees formed from one s and one p orbital.
dsp^3 hybridizationFive hybrid orbitals formed by one d, one s and three p orbitals with a trigonal bipyramidal arrangement.
d^2sp^3 hybridizationSix hybrid orbitals arranged octahedrally formed from two d, one s and three p orbitals.
molecular orbital modelA model that regards a molecule as a collection of nuclei and electrons where the orbitals extend over the entire molecule. The electrons are assumed to be delocalized rather than always located between a given pair of atoms.
molecular orbital (MO)Similar to atomic orbitals but for molecular probolems.
sigma molecular orbitalMO1 and MO2 electron distributions for molecular orbitals.
bonding molecular orbitalAn orbital lower in energy than the atomic orbitals of which it is composed.
hybridizationA mixing of the native orbitals on a given atom to form special atomic orbitals for bonding.
antibonding molecular orbitalAn orbital higher in energy than the atomic orbitals of which it is composed.
bond orderThe difference between the number of bonding electrons and the number of antibonding electrons, divided by two. It is an idex of bond strength
pi molecular orbitalTwo p orbitals that lie parallel overlap to produce two of these, one bonding and one antibonding.
paramagnetismA type of induced magnetism, associated with unpaired electrons, that causes a substance to be attracted into the inducing magnetic field.
diamagnetismA type of magnetism, associated with paired electrons, that causes a substance to be repelled from the inducing magnetic field.
heteronuclear diatomic molecule??
delocalized pi bonding??


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