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Chapter 8 AP Chem Flashcards

AB
bond energyThe energy required to break a given chemical bond.
square planar structureStructure with six electron pairs and the lone pairs at 180 degrees.
ionic compoundA compound that results when a metal reacts with a nonmetal to form a cation and an anion.
Coulomb's lawE = 2.31 x 10^-19 (Q1Q2/r)
bond lengthThe distance between the nuclei of the two atoms connected by a bond; the distance where the total energy of a diatomic molecule is minimal.
covalent bondingA type of bonding in which electrons are shared by atoms.
polar covalent bondA covalent bond in which the electrons are not shared equally because one atom attracts them more strongly than the other.
electronegativityThe tendency of an atom in a molecule to attract shared electrons to itself.
dipolarA molecule that has a center of positive charge and a center of negative charge is said to be this.
dipole momentA property of a molecule whose charge distribution can be represented by a center of positive charge and a center of negative charge.
isoelectronic ionsIons containing the same number of electrons.
lattice energyThe energy change occurring when separated gaseous ions are packed together to form an ionic solid.
single bondA bond in which one pair of electrons is shared by two atoms.
double bondA bond in which two pairs of electrons are shared by two atoms.
triple bondA bond in which three pairs of electrons are shared by two atoms.
localized electron (LE) modelA model which assumes that a molecule is composed of atoms that are bound together by sharing pairs of electrons using the atomic orbitals of the bound atoms.
lone pairAn electron pair that is localized on a given atom; an electron pair not involved in bonding.
bonding pairAn electron pair found in the space between two atoms.
Lewis structureA diagram of a molecule showing show the valence electrons are arranged among the atoms in the molecule.
duet ruleRule when two shared electrons are needed to form a stable molecule.
octet ruleThe observation that atoms of nonmetals tend to form the most stable molecules when they are surrounded by eight electrons (to fill their valence orbitals).
resonanceA condition occurring when more than one valid Lewis structure can be written for a particular molecule.
resonance structureElectron structures of a molecule that have more than one valid Lewis strucutre. Represented by a double arrow.
formal chargeThe charge assigned to an atom in a molecule or polyatomic ion derived from a specific set of rules.
molecular structureThe three-dimensional arrangement of atoms in a molecule.
valence shell electron-pair repulsion (VSEPR) modelA model whose main postulate is that the structure around a given atom in a molecule is determined principally by monimizing electron-pair repulsions.
linear structureTwo pairs of electrons with 180 degree bond angles of a molecule.
trigonal planar structureThee pairs of electrons with 120 degree bond angles and a flat structure.
tetrahedral structureFour pairs of electrons with 109.5 degree bond angles.
trigonal pyramidStructure with a lone pair and three identical electron pairs and atoms.
trigonal bipyramidShape of the structure with 5 electron pairs that produces minimum repulsion.
octahedral structureStructure formed by six electron pairs with 90 degree angle.
ionic bondingThe electrostatic attraction between oppositely charged ions.


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