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Chemistry: Chapter 5

AB
A form of energy that exhibits wavelike behavior as it travels through spacew like visible light, microwave, X-rays, TV and radio waveselectromagnetic radiation
the shortest distance between equivalent points on a continuous wave measured from crest to crest or trough to troughwavelength
the number of waves that pass a given point per secondfrequency
Equals one wave per secondone hertz
The waves height from the origin to the crest or from the origin to the troughamplitude
the speed of all electromagnetic waves including visible light3.00 X 10 to the eigth m/s in a vacuum
What is the symbol for speed of light?C
Product of its wavelength and its frequencyspeed of light
Light that has a longer wavelength has...a lower frequency
Light that has a shorter wavelength has a .......higher frequency
An example of white light that contains a continuous range of wavelengths and frequenciessunlight
What happens when sunlight passes through a prism?It is separated into a continuous spectrum of colors which are the colors of the visible spectrum
What is formed when tiny drops of water in the air disperse the white light from the sun into its component colors producing a continuous spectrum that arches across the sky?a rainbow
All forms of electromagnetic radiation with different frequencies and wavelengthselectromagnetic spectrum
What results from shorter wavelengths bending more than longer wavelengths as they pass through the prism?results in the sequence of colors red, orange, yellow, blue, indigo, and violet
How can you remember the sequence of colors?Roy G. Biv
What happens to energy as the frequency increases?Energy increases
How can you calculate the wavelength or frequency of any wave?use the formula light speed equals wavelength times frequency. Frequency is v.
The minimum amount of energy that can be gained or lost by an atom?quantum
He demonstrated mathematically that the energy of a quantum is related to the frequency of the emitted radiation by the equation energy=frequency times his constant.Planck
According to his theory, for a given frequency, matter can emit or absorb energy only in whole number multiples of hv; that is 1 hv, 2 hv, 3 hv, and so onPlanck
Electrons, called photoelectrons, are emitted from a metal's surface when a light of a certain frequency shines on the surfacephotoelectric effect
They power calculators by converting the energy of incident light into electrical energyphotoelectric cells
He proposed that electromagnetic radiation has both wavelike and particlelike natures. He calculated that a photon's energy depends on its frequency.Einstein
a particle of electromagnetic radiation with no mass that carries a quantum of energyphoton
the set of frequencies of the electromagnetic waves emitted by atoms of the elementatomic emission spectrum
How is light produced in the glowing tubes of neon signs?The light of a neon sign is produced by passing electricity through a tube filled with neon gas. Neon atoms in the tube absorb energy and become excited. The unstable atoms release energy by emitting light.
What is characteristic of the element being examined and can be used to identify that element?the atomic emission spectrum
The fact that only certain specific frequencies of light are emitted means that ....only certain specific frequencies of light are emitted
He proposed that the hydrogen atom has only certain allowable energy statesBohr
What is the lowest allowable energy state of an atom called?ground state
What state is an atom in when it gains energy?excited state
How did Bohr suggest that the single electron in a hydrogen atom move around the nucleus?only moves in certain circular orbits
The smaller the electron's orbit, the lower theenergy state or energy level
The larger the electron's orbit, the higher theenergy state or energy level
What does an atom emit corresponding to the difference between the energy levels associated with the two orbits?a photon
Derived an equation for wavelength of a particle of mass (m) moving at velocity (V) and predicted that electrons and all moving particles do indeed have wave characteristics.the de Broglie equation
States that it is fundamentally impossible to know precisely both the velocity and position of a particle at the same timethe Heisenburg uncertainty
What is the atomic model in which electrons are treated as waves?quantum mechanical model of the atom or the wave mechanical model of the atom
A three-dimensional region around the nucleus that describes the electron's probable location?atomic orbital
What does the Bohr atomic model assign to electron orbits?quantum numbers
What does the quantum mechanical model assign?principal quantum numbers (n) that indicate the relative sizes and energies of atomic orbitals
What does n specify?the atom's major energy levels
What are the atom's major energy levels called?the principle energy levels
What happens as n increases?the orbital becomes larger, the electron spends more time farther from the nucleus, and the atom's energy increases
How many energy levels have been detected for the hydrogen atom?Up to seven
How are sublevels labeled?s,p,d,or f according to the shape of the atom's orbital. All s are spherical and all p are dumbbell
The maximum number of orbitals related to each principal energy level equalsn squared
Because each orbital may contain at most two electrons, the maximum number of electrons related to eac principal energy level equals2n squared
How can a hydrogen atoms have so many energy levels, sublevels, and related atomic orbitals?At any given time, the atom's electron can occupy just one orbital
How many maximum electrons does each orbit contain?A maximum of two electrons
What do we call the arrangement of electrons in an atom?the atom's electron configuration
What arrangement do atoms tend to assume?the one that gives the atom the lowest possible energy
What is the most stable, lowest-energy arrangement of the electrons in atoms of each element?the element's ground-state electron configuration
This prinicipal states that each electron occupies the lowest energy orbital available?the aufbau principle
In the aufbau diagram, what does each box represent?an atomic orbital
All orbitals related to an energy level are of equalenergy.. all three 2p orbitals are of equal energy
In a multi-electron atom, the energy sublevels within a principal energy level have differentenergies...the three 2p orbitals are of higher energy than the 2s orbital
In order of increasing energy, the sequence of energy sublevels within a principal energy level iss,p,d,f
Orbitals related to energy sublevels within one principle energy level can overlap orbitals related to energy sublevels within anotherprincipal level
States that a maximum of two electrons may ocupy a single atomic orbital but only if the electrons have opposite spinsThe Pauli Exclusion Principle
An atomic orbital containing paired electrons with opposite spins is written as(up arrow)(down arrow)
States that single electrons with the same spin must occupy each equal energy orbital before additional electrons with opposite spins can occupy the same orbitalsHand's rule
A way of representing an electron's configuration by drawing a box for each of the atom's orbitalsorbital diagram
What does an empty box represent?An unoccupied orbital
What does a box containing a single arrow represent?an orbitral with one electron
What does a box containing both up and down arrows represent?a filled orbital
What is the orbital diagram for a ground-state carbon atom which contains two electrons in the 1s orbital, two electrons in the 2s orbital and 1 electron in two of three separate 2p orbitals?c (1s:up,down) (2s: up, down) (2p:up)(2p:up)(2p:empty box)
How many electrons does carbon (atomic number of 6 have)?6--number of electrons=number of protons
Another method of describing the arrangement of electrons in an element's atom by designating the principal energy level and energy sublevelassociated with each of the atom's orbital and including a superscript representing the number of electrons in each orbital is called...electron configuration notation
Noble gas notation is a method of representing noble gases usingbracketed symbols
Electrons in the atom's outermost orbitals, those generally associated with the atom's highest principal energy level which determine the chemical properties of an elementvalence electrons
simple shorthand method of writing valence electrons by using dotselectron-dot structure


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