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Chemistry: Chapter 25

AB
Chemical or nuclear reaction? Occurs when bonds are broken and formedchemical
Chemical or nuclear reaction? occur when nuclei emit particles and/or raysnuclear
Chemical or nuclear reaction?atoms remain unchanged although they may be rearrangedchemical
chemical or nuclear? atoms are often converted into atoms of another elementnuclear
Chemical or nuclear? Involve only valence electronschemical
Chemical or nuclear? may involve protons, neutrons, and electronsnuclear
Chemical or nuclear? associated with small energy changeschemical
Chemical or nuclear? associated with large energy changesnuclear
Chemical or nuclear? Reaction rate is influenced by temperature, pressure, concentration, and catalystschemical
Chemical or nuclear? reaction rate is not normally affected by temperature, pressure, or catalystsnuclear
He discovered x-rays and found that invisible rays were emitted when electrons bombarded the surface of certain materialsWilhelm Rogers
He accidentally discovered that phosphorescent uranium salts even when not exposed to light produced spontaneous emissions that darkened photographic platesHenri Becquerel
The concluded that the darkening of the photographic plates was due to rays emitted specifically form the uranium atoms present in the mineral sampleMarie Curie and husband Pierre
The process by which materials give off raysradioactivity
The rays and particles emitted by a radioactive source?radiation
Atoms of the same element that have different number of neutrons.isotopes
isotopes of atoms with unstable nucleiradioisotopes
unstable atoms lose energy by emitting one of several types of radiation to attain more stable atomic configurationsradioactive decay
What are the three most common types of radiationalpha, beta, and gamma
What kind of charge does an alpha particle carry?2+
What kind of charge does a beta particle carry?1-
Why aren't alpha particles very penetrating?because of their mass and charge, alpha particles are relatively slow moving compared with other types of radiation
What is a very fast moving electron that has been emitted from the neuron of an unstable nucleus?beta particle
Why do beta particles have greater penetrating power than alpha particles?They are lightweight and fast moving
These are high energy(short wavelength) electromagnetic radiation that carry no charge. The emission of these rays do not change the atomic number of the mass number of a nucleus.gamma rays
What determines the type of radioactive decay that will occur?neutron to proton ratio of the nucleus that determines the stability of an atom
What are nucleons?positively charged protons and neutral neutrons
Why are more neutrons needed as the atomic number increases?More neutrons are needed to produce a stong nuclear force that is sufficient to balance the electrostatic repulsion forces
This type of decay decreases the number of neutrons in the nucleus?Beta decay
What nuclei are radioactive and decay spontaneously?all nuclei with more than 83 protons
A radioactive decay process that involves the emission of a proton from the nucleus. A proton in the nucleus is converted into a neutron and a positron and then the positron is emitted.positron emission
A common radioactive decay process that decreases the number of protons in unstable nuclei by drawing in an electron which combines with the proton to form a neutron.electron capture
The particle emitted in (4/2 He), the mass number decreased by four and the atomic number increases by two.alpha decay
The particle emitted is (0/-1 B), the mass does not change but the atomic number increases by 1Beta decay
The particle emitted is (o/1 B), the mass number does not change but the atomic number decreases by 1positron emission
The particle emitted in this radioactive decay process is an x-ray photon, mass number does not change but the atomic number decreases by 1electron capture
The particle emitted is (0/0 y), the mass number does not change and the atomic number does not change.gamma decay
A series of nuclear reactions that begins with an unstable nucleus and results in the formation of a stable nucleusradioactive decay series
one element is converted into another element by the spontaneous emission of radiationradioactive decay
the conversion of an atom of one element to an atom of another elementtransmutation
His experiment demonstrated that nuclear reactions can be induced or produced artificiallyErnest Rutherford
The process which involves striking nuclei with high-velocity charged particlesinduced transmutation
Commonly called "atom smashers" are built to produce the high-speed particles needed to induce transmutationParticle accelerators
The elements immediately following uranium in the periodic table-elements with atomic numbers of 93 and greater that are produced in the lab by induced transmutation and are radioactive.Transuranium elements
The time required for one-half of a radioisotope nuclei to decay into its product.Half-life
Each radioisotope has its own characteristic ________ which remains constant regardless of changes in temperature, pressure, and concentration.half-life
The process of determining the age of an object by measuring the amount of a certain radioisotope remaining in that objectreadiochemical dating
A type of radiochemical dating that is commonly used to measure the age of artifacts that were once part of a living organism like the human skeletoncarbon dating
Carbon-14 only dates objects up to __________ years of age24,000
The decay process of what radioisotope is used to date objects such as rocks?uranium-238 to lead-206
How are energy and mass related?by Einstein's most famous equation. E=mc(squared). Change in energy(joules) is equal to the change in mass(kg) times the speed of light
Why is Einstein's equation of major importance for all chemical and nuclear reactions?It means that a loss or gain in mass accompanies any reaction that produces or consumes energy
What do we call the amount of energy needed to break one mole of nuclei into individual nucleons?nuclear binding energy
Why are elements with a mass number near 60 the most stable?because the binding energy per nucleon reaches a maximum around a mass number of 60
The mass of a nucleus is always less than the sum of the masses of the individual protons and neutrons that comprise itMass defect
The splitting of a nucleus into fragments which is accompanied by a very large release of energynuclear fission
The self-sustaining process in which one reaction initiates the next. The explosion from an atomic bomb.chain reaction
The chain reaction stops because neutrons escape the sample before causing sufficient fissions to sustain the reaction.subcritical mass
The chain reaction accelerates as neutrons cause more and more fissions to occursupercritical mass
nuclear fission produces the energy generated by nuclear reactors. This energy is used to primarily generateelectricity
What fuels the energy production of a nuclear reactor?a common fuel is fissionable uranium oxide encased in corrosion-resistant fuel rods
Reactors able to produce more fuel than they usebreeder reactors
How is the design of a nuclear power plant and that of a fossil burning plant similar?In both cases, heat from a reaction is used to generate steam. The steam is then used to drive turbines that produce electricity
How is the design of a nuclear power plant and that of a fossil fuel burning plant not similar?In a typical fossil fuel power plant, the chemical combustion of coal, oil, or gas generates the heat whereas in a nuclear power plant, a nuclear fission generates heat.
The binding together of two or more light (less than 60 mass number) and less stable nuclei to form a single more stable nucleusnuclear fusion
How is the sun powered?a series of fusion reactions as hydrogen atoms fuse to form helium atoms
Fusion reactions which have high energy requirements that are achieved only at extremely high temperatures and not practical for controlled electrical power generationThermonuclear reactions
uses a strong magnetic field to contain the fusion reactiona tokamak reactor
Why have scientists spent several decades researching nuclear fusion?because there is a trememdous abundance of lightweight isotopes such as hydrogen that can be used to fuel fusion reactions. Fusion reaction products are generally not radioactive
radiation energetic enough to ionize matter with which it collides is called...ionizing radiation
a radiation detection device that measures different radiation levels by measuring the electric currents produced by ionizing radiationthe geiger counter
a radiation detection device that uses a phosphorcoated surface to detect radiationscintillation counter
TV, watches, computer monitors all use these bright flashes of light that are produced when ionizing radiation excites the electrons in certain types of atoms called phosphors.scintillation
used to detect trace amounts of elements present in a sampleneutron activation analysis
can be used to follow a course of an element through a chemical reactionradioisotope
a radioisotope that emits non-ionizing radiation and is used to signal the presence of an element or specific substanceradiotracer
In this procedure, a radiotracer that decays by positron emission is injected into the patient's bloodstream.PET (positron emission transaxial tomography)
used to treat cancer by destroying the fast-growing cancer cellsradiation therapy
An atom or molecule that contains one or more unpaired electrons and is one example of the highly reactive products of ionizing radiation. They can affect a large number of molecules and ultimately disrupt the operation of normal cells.free radical
affects only nonreproductive body tissue and therefore affects the organism only during its lifetimesomatic damage
can affect offspring because it may not become apparent for several generationsgenetic damage
what two units are commonly used to measure radiation doses?rem and rod


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