| A | B |
|---|
| Making an Ald from a PRIMARY ALCOHOL... | use PCC in dichloromethane |
| Making an ald from an ALKENE (With at least one vinylic H)... | use O3 /// Zn, CH3CO2H |
| oxidative cleavage of a cyclic alkene will yield... | a dicarbonyl compound, that isn't in a ring anymore |
| The ways to form an ald are... | from prim alcs, from alkenes, reduce from carb acid |
| To create an ald from a CA... | 1. DIBAH, toluene solution, -78(o) C /// 2. H3O+ |
| To create a ket from a secondary alcohol... | various reagents, like PCC///CH2Cl2 |
| To prepare a ket from an alkene | works if one of the unsaturated C's is disubstituted, use O3///Zn, H3O+, yields a blah ketone and a H2C=O in this case |
| To prepare a ket from an aryl compound and an acid chloride | FRIEDEL-CRAFTS! circle thing + CH3C(=O)Cl and the reagent is AlCl3(cat)///heat, attaches it at the Cl |
| To make a methyl ketone... | H3O+///HgSO4 (catalyst) |
| a methyl ketone is... | blahblahblahC(=O)-CH3 |
| Ketones can also be made from CAs like... | (CH3)2Cu-Li+ /// Ether |
| The ways to make a ketone are... | from secondary alcohols, with ozone if double subst'd, F-C acylation of an aromatic ring, hydration of a terminal alkyne, from CA's |
