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Chapter 14 - Chemical Kinetics

AB
kineticsthe study of the rate of reactions and the steps by which they occur
collision theorymolecules must undergo forceful, properly oriented collsions for a reaction to occur
activation energyminimum amount of kinetic energy that colliding molecules must possess to react
activated complextheoretical transition structure between reactants and products
reaction ratethe speed at which reactants disappear or products appear
heterogeneous reactiona reaction in which the reactants are in different phases
catalysta substance that changes a reaction rate without being permanently changed or consumed by the reaction
homogeneous catalysta catalyst in the same phase as the reactants or in solution with a reactant
heterogeneous catalysta catalyst in a separate phase from the reactants
enzymebiological catalyst
inhibitora substance that binds to and reduces the effect of a catalyst
reaction mechanismthe series of steps that make up a reaction
elementary stepone of a series of steps in a reaction mechanism
rate-determining stepthe slowest elementary step in a reaction
complex reactiona reaction made up of multiple elementary steps
intermediatea substance formed in one step and used up in the next step
homogeneous reactiona reaction in which all the reactants and products are in the same phase
reaction orderan indicator of how the rate of a reaction is affected by that specific reactant's concentration
rate lawan equation that mathematically describes how fast a reaction can occur
specific rate constantthe experimentally determined rate for an individual reaction under specified conditions
pharmacokineticsthe study of how the human body processes medication
adsorptionthe collection of one substance on the surface of another



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