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A/S organic 3 - hydrocarbons matching & flash cards

alkenes & alkanes for A/s chemistry

AB
a hydrocarbon containscarbon and hydrogen only
a saturated hydrocarboncontains only single bonds
an unsaturated hydrocarbona C=C double bond
alkanes are ............... hydrocarbonsunsaturated
alkanes are ........ hydrocarbonssaturated
CH4 ismethane
C2H6 isethane
C3H8 ispropane
C4H10 isbutane
C2H4 isethene
C3H6 ispropene
C4H8 isbutene
There are two different compounds with the molecular formula C4H8; they are described asisomers
the two isomers of C4H8 areCH3.CH=CH.CH3 and CH3.CH2.CH=CH2
an alkene ........Br2(aq)readily decolourises
with Br2 and an alkene an ............. reaction occurselectrophilic addition
C2H4 + Br2 --->CH2Br.CH2Br
CH2Br.CH2Br is called1,2 dibromoethane
C2H4 + H2 --->C2H6
C2H4 + H2 --->C2H6 needs Ni; it's acatalyst
C2H4 + HBr --->CH3.CH2Br
CH3.CH2Br calledbromoethane
C2H4 + Cl2 --->CH2Cl.CH2Cl
CH2Cl.CH2Cl called1,2 dichlorethane
CH3.CH=CH2 + HBr --->CH3.CHBr.CH3
When a reactant like HBr is added to unsymmetrical alkene the (-) part of the reactantbonds to the C with less H
CH3.CH2.CH=CH2 + HBr --->CH3.CH2.CHBr.CH3
CH3.CH2.CHBr.CH3 called2-bromobutane
CH2=ch2 + potassium manganate-VII (purple)turns purple to colourless
all hydrocarbons burn in air and formCO2 & H2O
CH4 + Cl2 --> CH3Cl + ......HCl
CH4 + Cl2 --> CH3Cl + HCl is a .... reactionsubstitution reaction
CH4 + Cl2 --> CH3Cl + HCl conditionsbright sunlight or ultra violet
CH4 + Cl2 --> CH3Cl + HCl mechanism involvesfree radicals
CH4& Cl2 first stage of mechanism isCl-Cl ---> 2Cl*
Cl-Cl ---> 2Cl* called ......stageinitiation
CH4 + Cl* -->CH3* + HCl
CH4 + Cl* --> CH3* + HCl called .........stagepropagation
CH3* + Cl* --> CH3Cl called ......stagetermination
CH3Cl called...chlormethane
CH4 + Br2 -->CH3Br + HBr
CH3.CH2.CH3 + Br2 -->CH3.CH2.CH2Br + HBr
CH3.CH2.CH2Br called1-bromopropane
C3H8 used as acamping gas
C3H8 needs to be stored inpressurised containers
C8H18 present inpetrol
advantage of C8H18 over C3H8does not need a pressurised container for storage
The alkane with 20 C atoms ; molecular formula isC20H42
Alkene with 16 C atoms - molecular formula isC16H32
General formula for alkanes isCnH2n+2
General formula for alkenes isCnH2n

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