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Unit 8: Kinetics - Equilibrium

Unit 8: Kinetics - Equilibrium

AB
Reaction Ratethe speed at which reactants are converted into products in a chemical reaction
Collison Theoryin order for a chemical reaction/effective collision to occur, particles must collide with proper energy and proper alignment
Reaction Mechanismthe specific set of steps/reactions involved in an overall chemical reaction
Nature of Reactantsreactions involving ionic substances tend to ahve faster rates than reactions involving covalent substances
concentrationan increase in concentration of reactants will increase the rate of a chemical reaction
surface areaan increase in the surface area of reactants will increase the rate of a chemical reaction
pressurean increase in pressure will increase the rate of a chemical reaction (only for reactions involving gases)
catalystsubstance that is neither a reactant nor a product, but functions to speed up the rate of a chemical reaction by lowering activation energy/providing a shorter or "alternate" pathway
Temperaturean increase in temperature will increase the rate of a chemical reaction
equilibriumwhen 2 opposing processes are occurring at equal rates
physical edquilibriumwhen 2 opposing physical processes are occurring at equal rates; ex: phase equilibrium, solution equilibrium (saturation)
Phase equilibriumwhen the processes of freezing and melting or evaporating and condensing are occurring at equal rates
Solution Equilibriumwhen the processes of dissoving and precipitating are occurring at equal reates; when a solution has reached its saturation point
chemical euilibruiumin a chemical reaction, when the forward and reverse reactions are occurring at equal rates
Le Chatelier's Principlepredicts that when a stress is applied to a system at equilibrium, the system will shift to relieve the stress (stresses include temperature, pressure concentration)
Enthalpyheat energy absorbed or released during a chemical reaction
Entropya measure of the randomness or chaos associated with a chemical reaction
potential energy diagramsused to illustrate the energy lost or gained (reaction pathway) for a given chemical reaction
endothermic reactionschemical reactions that consume or require energy; chemical reactions in which energy is a reactant
Exothermic reactionschemical reactions that produce or release energy; chemical reactions in which energy is a product
Activated Complexan intermediate structure formed in the conversion of reactants to produts. The activated copmlex is the structure at the maximum energy point along the reaction path
activation energythe minimum energy required to convert reactants into the products; the difference between the energies of the activated complex and the reactants



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