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Unit 13 Kinetics and Equilibrium

AB
Reaction Ratethe speed at which reactants are converted into products in a chemical reaction.
Collision Theoryin order for a chemical reaction/effective collision to occur
Reaction Mechanismthe specific set of steps/rxns involved in an overall chemical reaction
Nature of Reactantsreactions involving ionic substances tend to have faster rates than reactions involving covalent substances.
Concentrationan increase in concentration of reactants will increase the rate of a chemical reaction
Surface Areaan increase in the surface area of reactants will increase the rate of a chemical reaction
Pressurean increase in pressure will increase the rate of a chemical reaction (only for reactions involving GASES!)
Catalysta substance that is neither a reactant nor a product
Temperaturean increase in temperature will increase the rate of a chemical reaction
Equilibriumwhen two opposing processes are occurring at equal rates
Physical Equilibriumwhen two opposing physical processes are occurring at equal rates; ex: phase equilibrium
Phase Equilibriumwhen the processes of freezing and melting or evaporating and condensing are occurring at equal rates
Solution Equilibriumwhen the processes of dissolving and precipitating are occurring at equal rates; when a solution has reached its saturation point
Chemical Equilibriumin a chemical reaction
Le Chatelier’s Principlepredicts that when a stress is applied to an equilibrium mixture
Enthalpythe heat energy absorbed or released during a chemical reaction
Entropya measure of the randomness or chaos associated with a chemical reaction
Potential Energy Diagramsused to illustrated the energy lost or gained (the reaction pathway) for a given chemical reaction
Endothermic Reactionschemical reactions that consume or require energy; chemical reactions in which energy is a reactant


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