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Chapter 5 Biochemistry

AB
aromatic acide is calledbenzoic acid
physical property of 1-9 saturated carbon atomsliquid
physical property more than 9 saturated carbon atomsodorless solid
physical property of unsaturated carboxylic acidsliquids
Carboxylic solubility 1-5 carbon atoms in HOH (water H20)soluble (the H-bonds with HOH)
carboxylic acids areweak acids
EsterificationHOH is produced from the (-OH) removed from the carboxylic acid and an H-lost by the alcohol
Estersproduced in reaction bewteen carboxylic acid and alcohol
Ester functional group
When naming an ester the first word is the name of the ________ and the 2nd word is the name of the _________ with the ending ( -oic acid ) replaced with ( -ate )alkyl of the alcohol; carboxylic acid
Physical property of esters with 1 to 9 carbons areliquid
Physical property of esters with lower molecular weights aresoluble in HOH (water)
An ester is neither an _____ or a ______acid; Base
Acid hydrolysis producescarboxylic acid and an alcohol
saponificationa reaction of a long-chain fatty acid and NaOH (makes soap)
ethyl alcohol in wine exposed to oxygen in air producesvinegar
carboxylic acids can be prepared fromprimary alcohols or aldehydes
the reason for the higher boiling points of carboxylic acids is that 2 carboxylic acids form hydrogen bonds between their carboxyl group results in a _______Dimer
When a dimer is formed the mass of the carboxylic acid isdoubled
Neutralization of carboxylic acid producescarboxylate salt and water
During exercisepyruvic acid is converted to lactic acid
Citric acidgives the sour taste to citrus fruits
Carboxylic acid reacts with an alcohol to form anEster
The aroma and flavor of many ______ are due to estersfruits
Esters with 2 to 5 carbons are __________ in HOH (water)soluble
solubility of esters in water ______ as the number of carbon atoms_________decrease; increase



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