A | B |
Amides | products of the amidation reactions; functional group-the hydroxyl group of a carboxyl group is replaced by a nitrogen group |
naming amides | dropping the ic acid (oic acid ) from the carboxylic acids names and adding the suffix amide |
Amides are ______ except formamide which is a liquid | solid |
Amines | contain 1 or more organic groups bonded to N-atom in compounds |
primary amine | 1 carbon atom is bonded to a N atom |
secondary amine | 2 carbon atom is bonded to a N atom |
tertiary | 3 carbon atom is bonded to a N atom |
naming amines | the alkyl groups bonded to the N-atom are listed in alphabetical order; prefixes di - and tri – are used for 2 or 3 identical substituents |
aromatic amines | use the name analine |
naming aromatic amines | Alkyl groups attached to the N of aniline are named with the prefix N-followed by the alkyl name |
Physical properties of amines, methyl, dimethyl, trimethyl and ethylamine are ______ | gases |
Amines solubility in H20 (HOH) | 1 - 6 atoms are soluble; 7 or more are not soluble |
Amine boiling points | lower than alcohol because polarity of (-NH) is lower than (-OH) |
amines react as _______ bases | weak |
amidation | amines react with carboxylic acid to form an amide |
Amides with _____ are soluble in H20 (HOH) | 1-5 carbons |
in Hydrolysis, ______ is added to an amide to split the molecule | H20 (HOH) |
products of hydrolysis of an amide are ______ | amine and carboxylic acid |
Function of dopamine | controls muscle movement, regulates sleep/wake cycle; improves cognition, attention, memory, learning |
Function of histamine | causes allergic reactions, inflammation, watery eyes, itching skin, hay fever, closure of throat in shellfish allergies |
Alkaloids | physiologic nitrogen containing compounds produced by plants, examples, nicotine, caffeine, morphine, etc |
Ammonia salts are _____ at room temperature and ______ in H20 | solid; soluble |
Naming salts of amines ______________is replaced with "amide" | the "oic acid" or "ic acid" in the correspnding carboxylic acid name |