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Chemistry 5 (Ch 12)

AB
Thomson model of an atomA ball of positive charge containing a number of electrons (plum pudding: neg elec in lump of pos pro). No explanation of # pro and neu or arrangement.
Rutherford model of an atomMost of atom's mass in small, pos charged region : nucleus, rest empty space with electrons surrounding nucleus
Bohr model of an atomElectrons travel around nucleus in definite orbits. Electrons have fuxed energy level
Orbitsconcentric paths
Quantum mechanical model of an atomNo definite shape, no precise orbits for electrons. 90% probability clouds. the modern description of the electrons in atoms
energy levelthe region around the nuclues where the electron is likely to be moving
Can electrons exist between energy levels?NO
Quantum of energyamount of energy required to move an electron from its present energy level to the next higher energy level
The higher the electron is placed on the energy ladder.....the farther away from the nucleus it is
Are rungs equally spaced on energy ladder?NO
How is the probability of finding an electron in a certain area in the QMM?A fuzzy cloud
Principal quantum numberthe principal energy level: 1,2,3, 4. ALSO number of sublevels within that principal energy level
Energy sublevelswhat electrons occupy: s, p, d, f
atomic orbitalsthe cloud shapes of probability of finding an electron in the QMM
nodesin p orbitals, regions close the nucleus where probability is low
s shapespherical
p shapedumbell
electron configurationsthe ways in which electrons are arranged around the nuclei of atoms
aufbau principleelectrons enter orbitals of lowest energy first
Are oribitals within a sublevel always =?YES
Pauli exclusion principlean atomic orbital may describe at most 2 electrons
Hund's rulewhen electrons occupy orbitals of equal energy, one electron enters each orbital until all orbitals contain one electron with spins parallel (2nd added to each so paired spins)
electromagnetic radiationincludes radio waves, microwaves, visible light, infrared and ultraviolet light, xrays, gamma rays
amplitude(of a wavelength) height of wave from origin to crest
wavelengthdistance between crests
frequencyin a travelling wave, the number of wave cycles to pass a given point per unit of time
spectrumwhen sunlight passes through a prism, light separates into a SPECTRUM of color
differences between visible lightred: longest wavelength, lowest frequency, blue: shortest wavelegth, greatest frequency
How does every element emit light if it is heated by passing electricity?it absorbes energy, then loses it which emits as light
atom emission spectrum(of an element) is given by passing the light emitted by an element through a prism (consists of relatively few lines)
What does each line of the atom emission spectrum correspond to?one exact freqyency of light being given off, or one exact amt of energy being emitted
Is the emission spectrum of each element unique to the element, or does it repeat?Unique
Energy to Frequency relationship: directly or inversely proportional?directly
photonslight quanta
photoelectric effectelectrons called photoelectrons are ejected by metals when light shines on them
Photoelectric effect will only occur when?When the frequency of light is above that of the threshold of energy
increase energy of photon in photoelectic effectincrease speed of electron
increase intensity of photon in photoelectric effectincrease number of photons striking metal
lyman serieslines at ultraviolet end (from higher to n = 1)
balmer serieslines in visible spectrum (from higher to n = 2)
paschen serieslines in infrared spectrum (from higher to n = 3)
How is energy absorbed or emitted?In packages, quanta
How does light behave?in Particles AND waves
de Broglie's equationpredicts that all matter exhibits wavelike motions
quantam mechanicsdescribes motions of subatomic particles and atoms as waves, and lose or gain energy in quanta
Heisenberg uncertainty principlestates that it is impossible to know exactly both velocity and position of a particle at the same time


Tucker High School

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