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O-Chem Chapter 12: Infared spectroscopy

AB
EM radiatoinlight and other forms fo radiant E
molecular spectroscopystudy of which frequencies of EM radiation are absorbed or emitted by substances and the correlation b/w these frequencies and specific types of molecular structure
vibrational infared regionportion of the infared region that extends from 4000 to 400 cm-1
infared spectroscopytechnique in which a compound is irradiated with infared radiation, absorption of which causes covalent bonds to change froma lower vibrational E level to a higher one; IR spec is good for det a molec's functional groups
wavenumberfrequencty of EM radiation expressed as the number of waves per cm
fingerprint regionportion of the vibrational infared region that extends from 1000 to 400 cm-1
conjugationsituation in which multiple conds aer separated by a single bond; a series of overlapping p orbitals; 1,3-butadiene is a conjugated diene; 3-buten-2-one is a conjugated enone
infared activebond must be polar, and its vibration must change the dipole moment fo the bond


Wimberley Danforth Junior High

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