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O-chem Chapter 22: Amines

AB
alipathic amineN is bonded only to alkyl groups
aromatic amineN is bonded to one or more aryl groups
heterocyclic amineN is one of teh atoms of the ring
heterocyclic aromatic amineN is one of the atoms of an aromatic ring
alkaloida basic N-containing cmpd of plant origin, many are physiologically active when administered to humans
quarternary ammonium ionion in which N is bonded to 4 Cs and bears a positive charge
Zwitterionan internal salt of an amino acid
diazonium ionan ArN2+ or RN2+ ion
Hofmann eliminationwhen treated with a strong base, a quartenary ammonium halide undergoes B-elimination by an E2 mech to give the less-sub alkene as the major product
Hofmann ruleany B-elimin. that occurs prefentially ro give the less sub alkene as the major product is said to follow the Hofmann rule


Wimberley Danforth Junior High

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