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A2 organic - amines

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AB
CH3.CH2.NH2 is calledethylamine
CH3.NH2 is calledmethylamine
CH3.CH2.CH2.NH2 is calledpropylamine
Amines have a lone pair of e on the N this makes thembases
The lone pair on the N is more available in amines than NH3 soamines are stronger bases
CH3.CH2.NH2 + HCl very dense white fumes calledethylammonium chloride
ethylammonium chloride is an example ofan amine salt
CH3.CH2.NH2 + HCl formula of product isCH3.CH2.NH3(+) Cl (-)
lone pair of e means N: bonds to H(+) bydative bonding
Because of lone pair of e on N it isalso a strong nucleophile
nucleophile is aelectron rich atom that is attracted to a (+) centre
CH3.CH2.NH2 + H2O formsCH3.CH2.NH3(+) OH (-)
CH3.CH2.NH2 + CH3.CO.Cl formsCH3.CO.NH.CH2.CH3 + HCl
CH3.CO.NH.CH2.CH3 calledN-ethyl ethanamide (C2H5 substituting on N)
CH3.CH2.CH2.NH2 + CH3.CO.Cl formsCH3.CO.NH.CH2.CH2.CH3 + HCl
CH3.CH2.NH3(+) Cl (-) & NaOH warm formsCH3.CH2.NH2 + NaCl + H2O
CH3.NH2 + HCl formsCH3.NH3(+) Cl(-)
CH3.NH3(+) Cl(-) calledmethyl ammonium chloride
CH3.NH2 + litmusturns red litmus blue
CH3.NH2 + CH3.CO.ClCH3.CO.NH.CH3 + HCl
CH3.CO.NH.CH3 calledmethyl ammonium chloride
CH3.NH2 + H2O formsCH3.NH3(+) + OH(-)
CH3.NH3(+) Cl(-) + NaOH heat formsCH3.NH2 + NaCl + H2O
CH3.CO.NH.CH2.CH2.CH3 calledN-propyl ethanamide
CH3.CO.NH.CH2.CH2.CH3 formed fromCH3.CH2.CH2.NH2 + CH3.CO.Cl
How can CH3.NH2 be formed from CH3.NH3(+) Cl(-)heat with NaOH (aq)
How can CH3.NH3(+) Cl(-) be formedCH3.NH2 + HCl
CH3.NH2 + CH3.I formsCH3.NH.CH3 + HI
CH3.NH2 + CH3.CH2.I formsCH3.NH.CH2.CH3 + HI
CH3.NH.CH3 can be formed from CH3.NH2by reaction with CH3I


Chemistry Activities
The King's School, Grantham

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