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A/s Haloalkanes

AB
CH3Br isbromomethane
CH3Cl ischlormethane
CH3I isiodomethane
CH3.CH2Br isbromoethane
CH3.CH2Cl ischloroethane
CH3.CH2I isiodoethane
CH3.CH2.CH2Br is1-bromopropane
CH3.CH2.CH2Cl is1-chloropropane
CH3.CH2.CH2I is1-iodopropane
CH3.CH2.CH2.CH2Br is1-bromobutane
CH3.CHBr.CH2.CH3 is2-bromobutane
CH3.CH2.CHBr.CH3 is also2-bromobutane
CH3.CHCl.CH2.CH3 is2-chlorobutane
CH3.CH2.CHI.CH3 is2-iodobutane
CH3.CH2Cl.CH3 is2-chloropropane
CH2I.CH2.CH3 is also1-iodopropane
CH3.CHCl.CH2.CH3 and CH3.CH2.CHCl.CH3 arethe same compound (they are just flipped over
CH3.CHCl.CH2.CH3 and CH3.CH2.CHCl.CH3 are both 2 chlorobutane becausethe substituting group is given the lowest no. possible
CH3.CH2OH can be converted to CH3.CH2Brby heating under reflux with KBr & H2SO4
KBr & H2SO4 willreplace OH by Br
PCl5 & CH3.CH2OH at room temperature willreplace OH by Cl (HCl gas also forms)
PCl5 & CH3.CH2OH will formCH3.CH2Cl
KBr & H2SO4 will formCH3.CH2Br
red P & Iodine with CH3.CH2OH at room temperaturereplaces OH by I
red P & Iodine with CH3.CH2OH formsCH3.CH2I
AQUEOUS NaOH or KOH with CH3.CH2Br heat under refluxBr replaced by OH
AQUEOUS NaOH or KOH with CH3.CH2Br heat under reflux formsCH3.CH2OH
CH3.CHBr.CH3 & KOH (aq) formsCH3.CHOH.CH3
NaOH or KOH (in alcohol NOT water)with CH3.CH2Br heat under refluxHBr is eliminated
NaOH or KOH (in alcohol NOT water)with CH3.CH2Br heat under reflux formsCH2:CH2 + HBr
CH3.CH2.CH2.CH2Br with alcoholic KOH formsCH3.CH2.CH:CH2 + HBr
CH3.CHBr.CH3 & KOH (aq) reaction type isnucleophilic substitution
CH3.CHBr.CH3 & KOH (aq) it's nucleophilic becauseOH(-) is attacking C+ on the C-Br
HBr + CH3.CH:CH2 formsCH3.CHBr:CH3
HBr + CH3.CH2.CH:CH2 formsCH3.CH2.CHBr:CH3
CH2Br.CH2.CH2.CH3 is1-brombutane
CH3.CHBr.CH2.CH3 is2-bromobutane
CH3.CH2.CHBr.CH3 is2-bromobutane also
CH3.CH2.CH2.CHBr.CH3 is2-bromopentane
CH3.CHBr.CH2.CH2.CH3 is2-bromopentane also


Chemistry Activities
The King's School, Grantham

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