A | B |
Temperature | Avg. KE of all particles |
calorimeter | insulated container to measure change in temperature |
heat capacity | amount of energy needed to raise temp. 1 deg. C |
specific heat capacity | amount of energy neeeded to raise 1g of substance by 1 deg. C |
enthalpy (H) | equal to the heat energy transferred at constant pressure |
entropy (S) | measure of disorder or positional possibilities |
heat of reaction | energy added or released during a rxn |
1000 J | 1 KJ |
Gibbs Free Energy (G) | can be used to determine if a reaction will be spontaneous |
4.18 KJ | 1000 calories (physics) |
activation energy | energy needed to get a rxn going |
heat of vaporization | energy required to change a liquid to a vapor |
enthalpy changes | equivalent to heat transferred during a phys/chem change |
endothermic | positive delta H values |
exothermic | negative delta H values |
Hess's Law | Enthalpy changes are the same no matter what pathway a given rxn takes |
-delta H and + delta S | always favored |
-delta H and -delta S | favored at lower temps |
+delta H and +delta S | favored at higher temps |
+delta H and - delta S | never favored |