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thermochemistry terms

AB
TemperatureAvg. KE of all particles
calorimeterinsulated container to measure change in temperature
heat capacityamount of energy needed to raise temp. 1 deg. C
specific heat capacityamount of energy neeeded to raise 1g of substance by 1 deg. C
enthalpy (H)equal to the heat energy transferred at constant pressure
entropy (S)measure of disorder or positional possibilities
heat of reactionenergy added or released during a rxn
1000 J1 KJ
Gibbs Free Energy (G)can be used to determine if a reaction will be spontaneous
4.18 KJ1000 calories (physics)
activation energyenergy needed to get a rxn going
heat of vaporizationenergy required to change a liquid to a vapor
enthalpy changesequivalent to heat transferred during a phys/chem change
endothermicpositive delta H values
exothermicnegative delta H values
Hess's LawEnthalpy changes are the same no matter what pathway a given rxn takes
-delta H and + delta Salways favored
-delta H and -delta Sfavored at lower temps
+delta H and +delta Sfavored at higher temps
+delta H and - delta Snever favored

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