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Chapter 6, Energy & States of Matter

J.K.'s chem 121.

AB
Specific heat is what?The amount of heat that raises the temperature of 1 g of a substance by 1 degree celsius.
Heat is measured in units of ______ ?Calories (cal) or joules ( J ).
Define a calorie.The amount of heat needed to raise the temperature of exactly 1 g of water by exactly 1 degree celsius.
How many calories (cal) in a kilocalorie (kcal)?1000 calories = 1 kilocalorie
One calorie is equal to how many joules?4.18 joules
One kilojoule equals how many joules?1000
What is also known as the nutritional "big" Calorie?the kilocalorie (kcal)
The heat gain or loss formula is …Heat gain or loss = (mass) X (temperature change {aka: Delta T}) X (specific heat)
Caloric values for the three food types are…?Carbohydrate = 4 kcal per gram, Fat (lipid) = 9 kcal per gram, protien = 4 kcal per gram.
True or false: all reactions occur at the same rate if the temperature is the same.False. Each reaction occurs at its own rate.
The rate (or speed) of a reaction depends on how quickly a ________ ?reactant or products concentration changes over time.
Exothermic or endothermic: Heat raised (feels warm)?Exothermic
Exothermic or endothermic: Heat is a product of the reaction.Exothermic
Exothermic or endothermic: A + B ---> C + heat.Exothermic
Exothermic or endothermic: heat absorbed (feels cool)Endothermic
Exothermic or endothermic: heat is a reactant in the reaction.Endothermic
Exothermic or endothermic: heat + C ---> A + BEndothermic
For a reaction to occur three things must happen. What are they?1. The molecules must collide. 2. They must collide effectively (at the proper oreintation). 3. Must collide with the minimum amount of energy (energy of activation).
The minimum energy necessary to cause a reaction to occur is ?the Energy of Activation.
Exothermic or endothermic: energy of products is less than reactants.Exothermic
In a reaction, what is the transition state?the point at which the activation energy is enough to cause the reaction to occur (the top of the hill).
In a reaction, what is an activated complex?the point at which the activation energy is enough to cause the reaction to occur (the top of the hill).
In an exothermic reaction, which side is the heat on, reactant or product?Product side. A + B ---> C + heat
In an endothermic reaction, which side is the heat on, reactant or product?Reactant side. heat + C ---> A + B
At the "activated complex" or "transition state", aka the top of the hill, what is happening?Reactant bonds are beginning to break and product bonds beginning to form.
What four things can you do to speed up a reaction?1. raise the temp. 2. increase the concentration. 3. pick better reactants (ionic rather than covalent bonds). 4. add a catalyst.
Does a catalyst bond with the reactants?No. A catalyst increases the rate of a reaction without being consumed.
Will a catalyst increase or decrease the energy of activation?it decreases or lowers the energy of activation.
What is a common catalyst used in labs?Platinum
What are the biological molecules that act as catalysts in human bodies called?enzymes (often protiens)
Define "equilibrium".it is a balance between reactants and products. The amount of product being formed by the forward reaction = the amount being lost by the reverse reaction.
true or false: Equilibrium means there are equal amounts or reactants and products.False. There may not be be equal amounts on both sides.
Equilibrium is when all __________ stops?all spontaneous change stops.
State "LeChatelier's Principle".Any system (reaction) at equilibrium will do whatever it takes to stay at or regain equilibrium.
What happens if you change the temperature after an exothermic reaction (system) is at equilibrium?a) An increase in temp drives it toward the reactants (K gets smaller). b) A decrease drives it toward the products (K gets larger).
What happens if you change the temperature after an endothermic reaction (system) is at equilibrium?a) An increase in temp drives it toward the products (K gets larger). b) A decrease drives it toward the reactants (K gets smaller).
What is hypothermia?Low body temperature due to prolonged exposure to cold.
What is normal body temperature in degrees celsius?37 degrees celsius.
What are the vital signs associated with hypothermia?Respiratory rate slows. Blood pressure decreases. Heart rate slows.
The symptoms of hypothermia due to cold actually happen because ___________?cellular enzymes become sluggish.
When body core temperature reaches 30-32 degrees celsius (87-90 degrees fahrenheit) what happens?shivering stops, body heat generating capacity is exhausted.
When body core temperature reaches 21 degrees celsius (70 degrees F) what happens?coma results then death due to cardiac arrest.
When you induce hypothermia what are you actually doing.You are slowing down chemical reaction rates in the body.
What are some practical uses of hypothermia in medicine?1. Chilling body organs for organ transplant. 2. Icing to reduce inflamation from injury. 3. Ice baths for someone with a high fever.
How many calories in the "heat of jusion" for water?80 calories
What is the "heat of fusion"?The heat energy required to change 1 gram of solid to liquid, or heat lost to freeze a liquid to a solid.
How many calories in the "heat of vaporization" for water?540 calories
What is the "heat of vaporization"?The heat energy required to change 1 gram of liquid to a gas (steam), or heat loss to condense from a gas to a liquid.


Bob P.

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