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Organic Chemistry

AB
hydrocarboncompound composed of carbon and hydrogen
saturatedcarbon-carbon bonds that are all single bonds
unsaturatedcarbon-carbon bonds that contain multiple bonds
alkanessaturated hydrocarbons (single bonds)
formula for alkaneCnH2n+2
when carbon atoms from long "strings" or "chains"normal, straight-chain, or unbranched hydrocarbons
meth1
eth2
prop3
but4
pent5
hex6
hept7
oct8
non9
dec10
the only shapes that organic molecules can taketetrahedral (109.5), trigonal planar (120), linear (180)
C6H14hexane
rule #1 for naming alkanesfind longest continuous chain of carbon atoms
rule #2 for naming alkanesnumber carbons, starting at end closest to any branching
rule #3 for naming alkanesuse appropriate name for each alkyl group, specify its position on parent chain
rule #4 for naming alkaneswhen alkyl group occurs more than once, attach prefix (di- tri-)
rule #5 for naming alkanesalkyl groups listed in alphabetical order, disregarding any prefix
alkeneshydrocarbons that contain carbon-carbon double bonds (unsaturated)
alkyneshydrocarbons with carbon-carbon triple bonds (unsaturated)
alkene formulaCnH2n
multiple carbon-carbon bonds result when...hydrogen atoms are removed from alkanes
#1 for naming enes or ynesselect longest chain of carbon atoms that contains the double or triple bond
#2 for naming enes or yneschange root name (2 -ene, 3 -yne)
#3 for naming enes or ynesnumber parent chain starting at end closest to double or triple bond
maximum # of atoms a given carbon atom can be attached to4; because carbon has four valence electrons
double bondshares two pairs of electrons; carbon dioxide
structural isomerismtwo molecules have the same atoms but different bonds; ex: butane as straight chain or isobutane as a branched-chain
because of different structuresstructural isomers have different properties
branch or substituentsmall chain of carbon atoms attached to a longer chain
alkylan alkane when it functions as a substituent
functional groupan atom or group of atoms in hydrocarbon derivatives that contains elements in addition to carbon and hydrogen
hydrocarbon derivativean organic molecule that contains one or more elements in addition to carbon and hydrogen
alcoholR-OH
CH3OHalcohol
etherR-O-R
CH3-O-CH3ether
ketonean organic compound containing the carbonyl group bonded to two carbon atoms (middle)
aldehydean organic compound containing the carbonyl group bonded to at least one hydrogen atom (end)
aldehydenamed by ending -al
ketonenamed by ending -one
alcoholnamed by ending -ol
carboxylic acidRCOOH

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